The fundamental principle of optical thin-film coatings relies on multi-beam interference. When light strikes a multilayer thin film composed of materials with varying refractive indices, it undergoes reflection and refraction at each interface. These beams superimpose and interfere. Constructive interference amplifies reflected/transmitted light intensity, while destructive interference reduces it. By adjusting material, thickness, and layer count, phase differences are controlled to selectively enhance or suppress specific wavelength transmission/reflection.
The advantages of metal reflective films are their simple preparation process and broad operational wavelength range, while their drawbacks include high optical losses and inherently limited maximum reflectivity. To enhance the reflectivity of metal reflective films, several dielectric layers of specific thickness can be deposited on the outer surface, forming metal-dielectric reflective coatings. It should be noted that while metal-dielectric coatings improve reflectivity at specific wavelengths or wavebands, they compromise the neutral reflection characteristics of pure metal films. All-dielectric reflective coatings operate based on multiple-beam interference principles. Contrary to anti-reflection coatings, depositing a film material with higher refractive index than the substrate on an optical surface increases reflectivity. The simplest multilayer reflector consists of alternating high and low refractive index materials deposited through vapor deposition, with each layer's optical thickness equivalent to a quarter-wavelength of a specific light wave. Under such conditions, the reflected light vectors at each interface share identical vibration directions, resulting in cumulative amplitude enhancement as the number of film layers increases.
Based on functionality and structure, optical thin-film coatings are commonly classified into the following types:
1. Single-layer coating
A single dielectric film deposited on a substrate, typically for anti-reflection (AR) or high-reflection (HR) purposes. It can be simplified as an equivalent interface for analyzing reflectance and transmittance. When the film thickness satisfiesnh = λ/4(n: refractive index,h: thickness,λ: wavelength), maximum/minimum reflectance is achieved. Ifn < √(n₀n₂)(n₀: incident medium refractive index,n₂: substrate refractive index), AR is realized; ifn > √(n₀n₂), HR is achieved. Perfect AR (n = √(n₀n₂)) requires rare materials.
2. Multilayer coating
Composed of multiple dielectric layers with varying refractive indices, used for high reflection, color separation, filtering, or polarization. Equivalent refractive index concepts simplify analysis. For quarter-wavelength-thick layers (nh = λ/4), two layers with refractive indicesn₁andn₂can be equivalent to a single layer withn_I = n₁²/n₂. Common designs include quarter-wave (QWOT) and half-wave (HWOT) stacks with alternating high/low or identical refractive indices.
3. Metal coating
A metallic film deposited on optical components for high reflection, beam splitting, or polarization. Reflectance/transmittance depends on the metal’s complex refractive index (n = n’ - in", wheren’andn"are real/imaginary parts). Metals exhibit strong absorption (largen") in visible wavelengths, yielding high reflectance and low transmittance. Common materials: Aluminum, Silver, Gold, Chromium.
4. Gradient coating
Dielectric films with refractive indices varying along thickness or position, used for dispersion correction, depolarization, or broadband AR. Gradient coatings minimize abrupt interface reflections. Types include:
· Thickness-gradient coating: Layer thickness varies spatially (e.g., wedge/taper).
· Index-gradient coating: Refractive index varies continuously (e.g., linear/exponential profiles).
1. Lasers: Laser systems require stable standing waves within resonant cavities to achieve stimulated emission and amplification. High-reflective or partially reflective optical dielectric coatings are applied at both ends of the cavity to form a feedback mechanism.
2. Optical Instruments: Components such as lenses, prisms, filters, beam splitters, and polarizers rely on optical dielectric coatings to enhance performance and stability. These coatings reduce reflection loss, increase transmittance, modify light color or polarization, and protect components from environmental factors like temperature, humidity, dust, and scratches.
3. Communication Systems: Devices including optical fibers, laser diodes, modulators, amplifiers, and switches utilize optical dielectric coatings to optimize efficiency and signal-to-noise ratio. They minimize insertion loss, boost output power, expand bandwidth, suppress feedback noise, and enable wavelength/mode multiplexing for higher system capacity and flexibility.
4. Solar Energy Utilization: Solar cells, thermal power systems, and lighting devices employ optical dielectric coatings to improve conversion efficiency and durability. These coatings enhance absorption, reduce reflection, regulate emissivity, suppress thermal radiation, and enable selective utilization or exclusion of specific solar wavelengths.
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